For the Chocolate Cake
Preheat oven to 350ºF. Grease and line 3 6-inch round cake pans with parchment paper. Set aside.
In a large bowl, add the dry ingredients; all purpose flour, cocoa powder, baking powder, baking soda and salt. Whisk to combine and set aside.
In the bowl of a stand mixer fitted with the paddle attachment, combine the softened butter, oil, sugar and brown sugar. Whisk on medium speed until creamy.
Add the vanilla extract, eggs and egg yolk. Continue beating until fully incorporated.
Add the dry ingredients, one cup at a time, alternating with 1/3 cup of buttermilk.
Pour the hot water and 1 tablespoon of espresso and continue beating for another minute.
Scrape the sides of the bowl and divide batter evenly among 3 cake pans. For exact measurements use a kitchen scale.
Bake for 25-30 minutes (you might need more depending on your oven), until toothpick inserted in the center comes out mostly clean (some crumbs is OK). Cool cakes for 15 minutes before transferring to a cooling rack.